Analysis of trace per- and polyfluorinated organic vapours in air using cryogen-free thermal desorption and GC-MS
This study describes the sampling and analysis of a challenging range of trace-level volatile and semi-volatile vapours of per- and polyfluorinated alkyl substances (PFAS) in air. The analytical system used combines modern single-quadrupole GC-MS technology and a TD100-xr™ automated thermal desorption (TD) system from Markes International, which operates without a liquid cryogen coolant and complies fully with relevant international standard methods. Excellent method performance (linearity, repeatability, storage stability, etc.) was demonstrated across the range of compounds tested, including low or sub-ppt detection limits for all compounds.